Nitrogen (N) is very important in plant growth and development by providing the building blocks for plant cell structure, carbohydrate production and protein synthesis. The nitrogen cycle is complex and very leaky as nitrogen compound transformations are influenced by microbial activity, cropland management, and the environment. Increasing nitrogen efficiency means getting more of the N into the plant in the form used by the plants when requirements are the highest. The chemical forms of nitrogen determine potential losses from the soil. Nitrate-N (NO3) has a negative charge and cannot be held by the soil cation exchange capacity (CEC) and therefore vulnerable to leaching with downward moving water. Ammonia-N (NH3) is a gas and can therefore be lost to the atmosphere by volatilization. Only ammonium-N (NH4) is positively charged and can be held by the soil CEC, however nitrification through microbial activity prevents N from being in this form for extended periods. There are several nitrogen fertilizer additives to keep N in chemical forms that are not vulnerable to loss which can result in greater N use efficiency.
Compounds that limit N losses from volatilization are applied to urea based N fertilizers that inhibit the active sites on the urease enzyme which then slows conversions of urea to ammonia (NH3) gas. Urease enzyme inhibition would be recommended when urea fertilizers are to remain on the soil surface waiting for precipitation to dissolve and move it into the soil. A very common and well known urease inhibitor is NBPT (N-(n-butyl) thiophosphoric acid triamide) which is currently marketed as several trade name products. Ammonium thio-sulfate fertilizer is also known to reduce urease activity but not as a consistent level as NBPT.
Nitrification inhibitors keep N as ammonium (NH4) by slowing nitrosomonas bacterial activity in the soil which are part of the conversion of NH4 to NO3. The two well know active ingredients are nitrapyrin and dicyandiamide (DCD). Use of these compounds would be recommended when N fertilizers are applied well in advance of heavy crop use therefore keeping N as ammonium (NH4) that is held to the soil CEC and protected from leaching. Cooler soil temperatures decrease nitrosomonas activity resulting in less ammonium to nitrate conversions. Therefore, nitrification inhibitors have typically been applied in the fall with anhydrous ammonia to keep N as ammonium until soil temps cool below 50° Fahrenheit. However, due to higher nitrogen fertilizer prices and environmental awareness, growers are considering protecting N with spring applications of nitrification inhibitors as well.
Drs. Goos and Franzen at North Dakota State University have completed extensive research on nitrogen fertilizer additives and have provided strong education resources. To learn more about nitrogen fertilizer additives please see Dr. Franzen’s Nitrogen Extenders for Nitrogen Fertilizers presentation.